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Neodymium
doped Yttrium Aluminum Garnet (Nd:Y3Al5O12
or Nd:YAG) crystal, which continues as the best of the rare earth
garnet materials that are characterized by four-level laser operation
which permits low threshold pulse and cw operation. It is the most mature
and widely used solid-state laser material adopted by R&D, medical,
industrial and military customers. Its main and obvious advantages are:
high gain, low threshold, high efficiency, low loss at 1.064 µm, as
well as high optical quality, good thermal conductivity and thermal
shock characteristics, stable chemical and mechanical properties, which
make Nd:YAG as the most suitable and commercial laser material for various
modes of operation (CW, pulsed, Q-switched, mode locked and cavity dumped).
Erbium doped Yttrium Aluminum Garnet (Er:Y3Al5O12
or Er:YAG) combines various output wavelength with the superior thermal
and optical properties of YAG. It is a well known material for medical
applications.
Ytterbium doped Yttrium Aluminum Garnet (Yb:Y3Al5O12
or Yb:YAG) is one of the most promising laser-active materials and
more suitable for diode-pumping than the traditional Nd-doped crystals.
It can be pumped at 0.94 µm and generates 1.03 µm laser output. Compared
with the commonly used Nd:YAG crystal, Yb:YAG crystal has a larger absorption
bandwidth in order to reduce thermal management requirements for diode
lasers, a longer upper-state lifetime, three to four times lower thermal
loading per unit pump power. Yb:YAG crystal is expected to replace Nd:YAG
crystal for high power diode-pumped lasers and other potential applications,
such as, its doubling wavelength is 515 nm, very close to that of Ar-ion
laser (514 nm) which makes it possible to replace large volume Ar-ion
laser. |
MAIN
PROPERTIES:
Chemical
formula |
Nd3+:Y3Al5O12 |
Er3+:Y3Al5O12 |
Yb3+:Y3Al5O12 |
Crystal
structure |
cubic |
cubic |
cubic |
Dopant
concentration, at.% |
0.7 -
1.1 |
up to 50 |
LOW: 6
- 8%, HIGH: 20%
|
Density,
g/cm3 |
4.56 |
5,35 |
4.56 |
Mohs hardness |
8.5 |
8.5 |
8.5 |
Thermal
expansion coefficient |
7.8 x
10-6 x °K-1, <111>
8.2 x 10-6 x °K-1, <100>
|
9,5 x 10-6
K-1 (a axis), 4,3 x 10-6 K-1 (b axis),
10,8 x 10-6 K-1 (c axis) |
7.8 x 10-6
x °K-1, <111>, 0 - 250 °C |
Thermal
conductivity at 25°C, W x cm-1 x °K-1 |
0.14 |
0.12 |
0.14 |
Loss coefficient
at 1064 nm, cm-1 |
0.003 |
0.003 |
0.003 |
Refractive
index, at 1 µm |
1.82 |
1.837 |
1.82 |
Lasing
wavelength, nm |
1064.0 |
2940 |
1030 |
Rods with round
cross-sections are manufactured:
Diameter,
mm |
(4
÷ 8) ± 0.025 |
Length,
mm |
up
to 130 ± 0.5 |
Flatness |
<
λ/10 |
Parallelism,
arc sec |
<
10 |
Perpendicularity,
arc min |
<
10 |
Roughness,
scratch/dig |
10
- 5 |
We
supply rods and slabs with different cross-sections, dimensions
and coatings. Different dopants compositions with different concentrations
are available for specific customer requirements.
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