|
The photorefractive
effect is a phenomenon whereby the local index of refraction is
modified by spatial variations of the light intensity. It is strongly
observed when coherent rays interfere with each other in a photorefractive
material which forms a spatially varying pattern of illumination. As
a result, charge carriers are produced in the material which migrate
owing to drift or diffusion and space charge separation effects. The
resulting electric field that is produced, induces a refractive index
change via the electro-optic effect. Some of the applications are spatial
light modulators, 4 wave mixing, phase conjugation, optical memory and
computing. |
Sillenite single crystals Bi12SiO20 (BSO) and
Bi12GeO20 (BGO) show unique combination of
different physical properties. BSO and BGO crystals are very efficient
photoconductors with low dark conductivity that allow a build-up of
large photo-induced space-charges. Also strong spectral dependence of
the photoconductivity and their electrooptic properties allow to develop
and produce a wide range of optical devices and systems. BSO and BGO
crystals are used in spatial light modulators, dynamic real-time
hologram recording devices, phase conjugation wave mixing, optical correlators,
and optical laser systems for adaptive correction of ultrashort light
pulses. Photo-induced absorption make it possible to develop and produce
ô light-lightö type of optical devices such as optical modulators,
switches etc. The fabrication Sillenite Oxide thin-film crystal
structures by different technique permits the development of a long
list of devices including optical waveguides, integrated optical devices.
The use of waveguide optical structures based on Sillenites allows to
achieve uniform illumination (normally to the plane of waveguide) in
a wide spectral range.
The relatively large electrooptic and Faraday
effect of Sillenite Oxides makes them useful for optical fiber electric/magnetic
fields sensors. We are able to deliver undoped BSO and BGO crystals
both in small quantity for scientific research and in large quantity
for industry purposes. Along with 2x2x2 - 25x25x25 mm3 crystals,
we also offer crystal plates with aperture of up to 30x30 mm2
and thickness of 0.5 - 5 mm with ITO (Indium Tin Oxide) coatings on
request.
Strontium-Barium Niobate (SrxBa(1-x)Nb2O6)
SBN is an excellent optical and photorefractive material. Nominally
pure and doped by Ce, Cr, Co, Fe. SBN crystals of different compositions
are used in elecro-optics, acousto-optics, and photorefractive non-linear
optics. A new growing technique provides excellent optical quality single
crystals, free of growth striations, inclusions and other inhomogeneities,
as well as definite cross section and linear dimensions of up to 80mm.
SBN crystalline elements meet the requirements for different applications.
Based on this unique crystal growing technique, large high quality SBN
optical elements and photorefractive cells are available, Fe:LiNbO3
(other dopants are available).
Iron doped Lithium Niobate crystal (Fe:LiNbO3)
is a kind of commonly used photorefractive material with high electro-optical
(EO) coefficients, high photorefractive sensitivity and diffraction
efficiency. Compared to BaTiO3 series photorefractive crystals,
it has some outstanding advantages, such as easy operation and storage,
low cost and large size availability, which make it more suitable for
volume fabrication and practical devices. Therefore, Fe:LiNbO3
crystal will forecast a wide range of applications. MolTech offers crystals
with different Fe doping concentration, dimensions and optical processing
requirements.
MAIN PROPTERTIES:
Crystal
|
Bi12SiO20
(BSO)
|
Bi12GeO20
(BGO)
|
Fe:LiNbO3
|
SBN
x=0.60
|
SBN
x=0.75
|
Crystal
Structure |
cubic, point
group: 23 |
cubic, point
group: 23 |
Trigonal,
3m
|
4mm
|
4mm
|
Lattice(Cell)
Parameters, Å |
10.10 |
10.15 |
-
|
a = 12.46, c = 3.946
|
a = 12.43024, c = 3.91341
|
Transmission
Range, µm |
0.4-6 |
0.4-7 |
0.35 - 5.5
|
0.3
5- 6.0
|
0.35
- 6.0
|
Refractive
Index at 0.63µm |
2.54 |
2.55 |
2.20
(ne), 2.29 (no)
|
ne
= 2.33, no = 2.36 @0.51µm
|
ne
= 2.35, no = 2.37 @0.51µm
|
Electro-Optic
Coefficient r41, pm/V |
5.0 |
3.5 |
r22=6.8,
r31=10, r33=32
|
r13=47,
r33=235
|
r13=67,
r33=1340
|
Optical
Activity, deg/mm at 500 nm |
42 |
41.5 |
-
|
-
|
-
|
- deg/mm at 600 nm |
25 |
24 |
-
|
-
|
-
|
Density,
g/cm3 |
9.15 |
9.2 |
4.64
|
5.4
|
5.4
|
Mohs
Hardness |
5 |
5 |
5
|
5.5
|
5.5
|
Melting
Point, C |
890 |
920 |
1255
(Tc=1140 )
|
1500 ± 10°C
|
1500 ± 10°C
|
Dielectric
Constant |
56 |
40 |
85
(e11) 30 (e33)
|
880
|
3400
|
Dark
Resistance, Ohm cm |
1014 |
1014 |
-
|
-
|
-
|
Absorption
coefficient @0.44µm |
- |
- |
-
|
0.3cm-1
|
-
|
Thermal
conductivity @25°C |
- |
- |
-
|
|
0.006 W/cm*K
|
@1370-1470°C |
- |
- |
- |
-
|
0.008 W/cm*K
|
Thermo-optic
coefficient dne/dT |
- |
- |
-
|
3x10-4K-1
|
-
|
Curie
temperature |
- |
- |
-
|
75°C
|
56°C
|
Half
wave Voltage |
- |
- |
-
|
240 V
|
48 V
|
We supply rods or
slabs, made from mentonied photorefractive crystals with different cross-sections
and dimensions. Different dopants with different concentrations are
available for specific customer requirements.
|