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Due to significant
absorption in the near infrared in pure L-arginine phosphate monohydrate
(LAP), deuterated LAP (DLAP) crystals have been grown using heavy water
(D2O) as a solvent by a slow cooling technique. The growth
conditions for the growth of monoclinic dLAP crystals are optimized
by adjusting the growth parameters, such as pH, temperature etc. The
grown crystals are morphologically compared with the pure LAP crystals.
Deuterated L-arginine phosphate C6D14N4O2
· D3PO4 is a promising non-linear optical
material having good non-linear coefficient, high damage threshold as
compared to L-arginine phosphate(LAP) and potassium dihydrogen phosphate
(KDP).
APPLICATIONS:
Second,
third and fourth harmonic generation from the fundamental radiation
1.06 µm |
Sum
and difference frequencies generation in wide spectral range from
UV to IR |
Literature:
|
A.S. Haja Hameeda, G. Ravia, R. Ilangovana, A.
Nixon Azariaha, P. Ramasamyb. Growth and characterization of deuterated
analog of l-arginine phosphate single crystals. Journal of Crystal
Growth 237239 (2002) 890893 |
|
Atsushi Yokotani, Takatomo Sasaki, Kunio Yoshida,
and Sadao Nakai. Extremely high damage threshold of a new nonlinear
crystal L-arginine phosphate and its deuterium compound. Appl.
Phys. Lett. 55(26) 2692 (25 Dec 1989) |
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MAIN
PROPERTIES:
Transparency range, nm |
220 - 1300 |
Symmetry, space group |
monoclinic, P21 |
Lattice parameters, Å |
a = 10.75; b = 7.91; c = 7.32; Z = 2; ß
= 98.0 |
Mohs hardness |
3 |
Refractive indexes: |
|
at 1064 nm |
nx = 1.4973; ny = 1.5590;
nz = 1.5674 |
at 532 nm |
nx = 1.5117; ny = 1.5794;
nz = 1.5884 |
at 355 nm |
nx = 1.5352; ny
= 1.6078; nz = 1.6211 |
Non-linear coefficients, pm/V |
d23
= - 0.84, d25 = - 0.58 |
Decomposition temperature, °C |
130 |
Optical absorption, cm-1 for DLAP |
0.02 at 1064 nm, 0.01 at 532 nm,
0.04 at 355 nm |
Optical damage threshold, GW/cm2,
outside matching at 1053 nm, 23 nsec or 526 nm, 20 nsec |
> 10 |
Chemical properties |
hygroscopic |
We supply DLAP optical
elements made according to customers' order. |