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ß-Barium
Borate (ß-BaB2O4 or BBO) is an excellent
optical non-linear crystal recently developed. It exhibits broad phase
matching range, high non-linearity (about 6 times more than that of
KDP), high optical damage threshold, good mechanical and temperature
stability. This trigonal uniaxial crystal possesses wide transparency
range from 0.19 to 3.3 µm. Its useful transmission range (<5%/cm)
is 0.21 to 2.1 µm and it has been demonstrated to be efficient
for the generation of second harmonic radiation down to about 0.21
µm. It is also useful for broadly tunable optical parametric
oscillators (OPOs) and amplifiers (OPAs). Autocorrelation applications
may be performed down to 0.19um. Its exceptional IR transmission and
wide thermal acceptance bandwidth allow high average power OPO/OPA
operation, with minimal heating from long wavelength idler radiation.
BBO's relatively narrow angular acceptance bandwidth
(especially in the UV) may limit its usefulness in certain applications
involving lasers with less than diffraction limited beam quality.
Its mild hygroscopicity should not limit its usefulness in most circumstances.
BBO's broad phase-matchability makes it an excellent
candidate for general use with Nd:YAG and other Q-switched/mode-locked
solid-state lasers. When using a tunable Ti:sapphire, Alexandrite or dye
laser, BBO can be used to generate tunable radiation from the near
IR to the UV. Such high power, widely tunable radiation would be useful
for many applications, including spectroscopy, medicine, materials
processing, nonlinear optics, LIDAR, remote sensing, and photochemistry.
In the commercial market, solid state nonlinear systems based on BBO
could compete with dye lasers, and have the advantage of lower operating
cost and more convenient tuning over large frequency ranges.
APPLICATIONS:
For harmonic generation (SHG, THG, 4HG, 5HG) of
Nd:YAG laser, SHG, THG of Ti: Sapphire, Alexandrite lasers
For tunable solid state lasers using OPO (pumped
by 355, 532 or 1064 nm)
For UV sources from SHG, SFG of dye lasers
For autocorrelation (in thin plates) in shortpulse
(ps and fs) lasers
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MAIN PROPERTIES:
Transparency
range, nm |
190 -
2600 |
Point
group |
3m |
Space
group |
R3c |
Lattice
parameters, Å |
a = 12.532;
c = 12.717 Å |
Density,
g/cm3 |
3.85 |
Mohs
hardness |
4 |
Refractive
indexes: |
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at 1064
nm |
ne
= 1.5425; no = 1.6551 |
at 532
nm |
ne
= 1.5555; no = 1.6749 |
at 355
nm |
ne
= 1.5775; no = 1.7055 |
at 266
nm |
ne
= 1.6139; no = 1.7570 |
at 213
nm |
ne
= 1.6742; no = 1.8465 |
Non-linear
coefficient, pm/V |
d22
= 1.6; d31 = 0.08 |
Cut off
SHG |
Type
I
- 411 nm; Type II - 527 nm |
Work
off |
Type
I, 1064 nm - 3.2° |
Temperature
acceptance |
Type
I, 1064 nm - 55 °C "cm |
Optical
damage threshold |
1 - 2
GW/cm2 (1064 nm, 10 ns) |
Conversion
efficiency, % |
30 (1064
nm, 20 ns, 3 W) |
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35 (1780
nm, 20 ns, 20 Hz, 2 W) |
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20 (1064
nm, 20 ns, 50 Hz, 2 W) |
We supply BBO
optical elements made according to customers' order.
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