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Birefringent Optical Crystals
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Calcite CaCO3birefringence
The division of light into two components (an "ordinary" and an "extraordinary ray") found in materials have two different indices of refraction in different directions (i.e. when light entering certain transparent materials, such as calcite, splits into two beams which travel at different speeds). Birefringence is also known as double refraction. Crystals possessing and exhibiting birefringence include hexagonal (such as calcite), tetragonal, and trigonal crystal classes, and are known as uniaxial. Orthorhombic, monoclinic, triclinic exhibit three indices of refraction. They are therefore trirefringent and are known as biaxial. Birefringent prisms include the Nicol prism, Glan-Foucault prism, Glan-Thompson prism, and Wollaston prism.
  Another material, an excellent birefringence optical crystal undoped YVO4 is newly developed. It has very good transmission in a wide wavelength range from visible to infrared, large index of refractivity and birefringence difference. Compared to other important birefringence crystals, YVO4 has higher hardness, better fabrication property, water insoluble and man-made than calcite (CaCO3 single crystal); easier to get large, high quality crystal and lower cost than rutile (TiO2 single crystal). Those outstanding properties make YVO4 very important birefringence optical material and widely used in opto-electronic research, development and industry. For example, the optical communication system needs a huge quantity devices of undoped YVO4, such as fiber optical isolators, circulators, beam displacers, Glan polarizers and other polarizing devices.
   We deliver all kinds of birefringent crystals, especially the YVO4 and TiO2 crystals and parts made from them for passive optical and polarization components. If you have any need for birefringent crystals, please feel free to contact us. Our engineers will help you choose the most suitable crystal for your application. The highest quality and lowest prices are our commitments.

Crystal
Birefringence D=he-ho
Refractive index h at l= 0.63 µm Thermal optical Coef. dh/dT 10-6/°K Structure and lattice constant, Å Melting point °C Density g/ cm3 Hardness (Mohs) Thermal Coef. 10-6/K
TiO2
(rutile)
+ 0.282
ho=2.583
he=2.865
a: -0.72
c: -0.42
Tetragonal a=4.593  c=2.958 1840 4.26 7 a: 7.14
c: 9.19
YVO4
+ 0.222
ho=1.9929
he=2.2154
a: -8.5
c: -3.0
Tetragonal a=7.12, 
c= 6.29
1825 4.22 5 a: 4.46
c: 11.37
CaCO3
(calcite)
- 0.1705
ho=1.6557
he=1.4852
- Rhomb. a= 4.989
c= 17.062
1339 2.715 3 a:24.39
c: 5.68
PbMoO4
- 0.124
ho=2.386
he=2.262
a: 0.41
c: 0.72
Tetragonal a=5.435  c=12.11 1065 6.9 3 -
TeO2
(paratellurite)
- 0.118
ho=2.260
he=2.142
- Tetragonal a=4.81  c=7.613 730 5.99 4.5 -
LiNbO3
- 0.086
ho=2.286
he=2.203
a: 0.53
c: 5.60
Hexagonal a=5.15
c= 13.86
1255 4.64 5 a: 16.7
c: 2.0
MgF2
+ 0.012
ho=1.3836
he=1.3957
- Tetragonal a=4.64  c=3.06 1312 3.18 3 a: 13.7
c:8.48
SiO2
(quartz)
+ 0.009
ho=1.5427
he=1.5518
- Hexagonal a=5.15
c= 13.86
1610 2.66 5 7.07

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